Step 1: Click here to open up your business manager by going to https://business.facebook.com/settings.
Step 2: Once you are in your business manager, click on your ad account.
Step 3: Click on the 9 dots under the "house" icon on the right of the ad account to open the modal. Once the modal opens, click on "billing".
Step 4: Click the "payment settings" button on the right side of the page.
Step 5: Click "edit" to change your payment method.
Step 6: Update your information and then click "save".